Stumped! Episode 2: A Bondi Detective mystery

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Amyl nitrites are useful as reagents in a modification of the Sandmeyer reaction; the reaction of the alkyl nitrite with an aromatic amine in a halogenated solvent produces a radical aromatic species, this frees a halogen atom from the solvent. For the synthesis of aryl iodides diiodomethane is used, whereas bromoform is the solvent of choice for the synthesis of aryl bromides. Amyl nitrite, in common with other alkyl nitrites, is a potent vasodilator.

Amyl nitrite may be used during cardiovascular stress testing in patients with suspected hypertrophic cardiomyopathy to cause vasodilation and thereby reduce afterload and worsen an otherwise occult left ventricular outflow tract obstruction. Alkyl nitrites are a source of nitric oxide, which signals for relaxation of the involuntary muscles. Physical effects include decrease in blood pressure, flushing of the face, increased heart rate and relaxation of involuntary muscles the blood vessel walls and the internal and external anal sphincter.

There are no withdrawal symptoms. Overdose symptoms include nausea , hypotension , shortness of breath , fainting ; the effects set in quickly within a few seconds and disappear within a few minutes. Amyl nitrite may intensify the experience of synesthesia. Kjonaas, Richard A..

Journal of Chemical Education. Editorial on the use of the word "amyl". He began his career in the United Kingdom in the s, relocating to the United States in the s, his career-defining roles were in the British television series Danger Man and the surreal psychological drama The Prisoner , which he co-created. Shortly after he was born, McGoohan's parents moved back to Mullaghmore , County Leitrim and seven years they emigrated to Sheffield, England. There he attended Ratcliffe College , where he excelled in boxing. McGoohan left school at the age of 16 and returned to Sheffield, where he worked as a chicken farmer, a bank clerk, a lorry driver before getting a job as a stage manager at Sheffield Repertory Theatre.

When one of the actors became ill, McGoohan was substituted for him. In , McGoohan starred in a West End production of a play called Serious Charge in the role of a priest accused of being homosexual. Welles said in that he believed McGoohan "would now be, I think, one of the big actors of our generation if TV hadn't grabbed him, he can still make it. He was tremendous as Starbuck. He had an uncredited role in The Dam Busters , he delivered the line — "Sorry, old boy, it's secret — you can't go in. Now, c'mon, hop it! He could be seen in Zarak for Warwick Films. He did Ring for Catty on stage in While working as a stand-in during screen tests, McGoohan was signed to a contract with the Rank Organisation.

After some clashes with the management, the contract was dissolved. It appeared in a BBC television production in August Michael Meyer thought that McGoohan's performance in Meyer's translation of Brand in was the best and most powerful performance he'd seen.

It was McGoohan's last appearance on stage for 28 years. Soon, production executive Lew Grade approached McGoohan about a television series in which he would play a spy named John Drake. Having learned from his experience at the Rank Organisation, he insisted on several conditions in the contract before agreeing to appear in the programme: all the fistfights should be different, the character would always use his brain before using a gun, much to the horror of the executives, no kissing; the series debuted in as a half-hour programme geared toward an American audience.

It did well, but not as well as hoped. Production lasted 39 episodes. After this first series was over, one interviewer asked McGoohan if he would have liked the series to continue, to which he replied, "Perhaps, but let me tell you this: I would rather do twenty TV series than go through what I went through under that Rank contract I signed a few years ago and for which I blame no one but myself. McGoohan appeared in One Dead, shot in Sweden. McGoohan was one of several actors considered for the role of James Bond in Dr. While McGoohan, a Catholic, turned down the role on moral grounds, the success of the Bond films is cited as the reason for Danger Man being revived.

After he had turned down the role of Simon Templar in The Saint , Lew Grade asked him if he would like to give John Drake another try; this time, McGoohan had more say about the series. Danger Man was resurrected in as a one-hour programme; the scripts now allowed McGoohan more range in his acting.

The popularity of the series led to McGoo. Michael Strong Michael Strong was an American stage and television actor. He played Dr. He died of cancer in Los Angeles, California on September 17, , aged Allan M. From Wikipedia, the free encyclopedia. This article does not cite any sources. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. September Learn how and when to remove this template message. Categories : Columbo seasons American television seasons American television seasons. Hidden categories: Articles lacking sources from September All articles lacking sources.

Revision History. Gena Rowlands. Related Images. YouTube Videos. Title card from the first episode of Season 1. Top left: Dennis Weaver in McCloud.

Top right: Richard Boone in Hec Ramsey. Bottom left: Peter Falk in Columbo. Richard Wayne Van Dyke is an American actor, comedian, singer, and dancer, whose entertainment career has spanned seven decades. Carol Burnett and Dick Van Dyke in Established in , it is one of six United States senior military colleges.

The Summerall Guards performing the Citadel Series.

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Summerall Chapel faces the Parade Grounds. Vaughn c. Vaughn at a memorabilia event in March Virginia Cathryn "Gena" Rowlands is an American actress, whose career in film, stage, and television has spanned over six decades. Rowlands at the Cannes Film Festival. Daniel Patrick Harrington Jr.

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His father, Pat Harrington Sr. Harrington as host of Stump the Stars , Pat Harrington Jr. Lawrence Samuel Storch is an American comedian, actor and voice artist best known for his comic television roles, including voice-over work for cartoon shows, such as Mr. An Emmy Award, or simply Emmy, is an American award that recognizes excellence in the television industry, and is the equivalent of an Academy Award, the Tony Award, and the Grammy Award.

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Jane Greer was an American film and television actress who was perhaps best known for her role as femme fatale Kathie Moffat in the film noir Out of the Past. With Robert Mitchum in Out of the Past.

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Daniel Patrick Macnee was a British film and television actor. He was best known for his role as the secret agent John Steed in the British television series The Avengers. Macnee in an episode of Columbo , May Warren as Cinderella, pictured with Stuart Damon as the Prince. Robert Conrad is a retired American film and television actor, singer, and stuntman. Collin Wilcox was an American film, stage and television actress. Kjellin was well established as a film actor when he occasionally took on roles in television shows.

Image: Barbara Bain Mission Impossible Antoinette Bower is a retired American film, television and stage actress, whose career lasted nearly four decades.

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Bower and Raymond Massey as guest stars on Adventures in Paradise , Michael Strong was an American stage, film and television actor. Strong in trailer for Detective Story Joyce Benignia Van Patten is an American stage, film, and television actress, best known for the wry, astringent, and neurotic characters she portrays. He began his career in the United Kingdom in the s, relocating to the United States in the s. McGoohan in All Night Long Madeleine Sherwood was a Canadian actress of stage, film and television.

Sherwood in Cat on a Hot Tin Roof A variety of isomers are known, but they all feature an amyl group attached to the nitrite functional group. The alkyl group is unreactive and the chemical and biological properties are mainly due to the nitrite group. An early container of amyl nitrite, Hunterian Museum, Glasgow. Bernard Lawson, better known as Bernard Fox, was a Welsh actor. He is best remembered for his roles as Dr. Fox in Hogan's Heroes Werner as Guy Montag in Fahrenheit She was featured in major films such as Cecil B.

Robert Brown is a television actor who was most active in the s and s. Patricia Barry was an American stage, film, and television actress. Stephen Elliott appearing in Columbo, Pericles was a prominent and influential Greek statesman, orator and general of Athens during its golden age — specifically the time between the Persian and Peloponnesian wars.

Bust of Pericles bearing the inscription "Pericles, son of Xanthippus, Athenian". Marble, Roman copy after a Greek original from c.

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Aspasia of Miletus c. Anaxagoras and Pericles by Augustin-Louis Belle — She has frequently appeared in comedies throughout her career, while also earning critical recognition in dramatic films. Diaz receiving her star on the Hollywood Walk of Fame in June From this Article.